Most formula sheets are a wall of symbols. That is fine in an exam, where you already know what each line is for, and useless the week before, when the question is which line to reach for. The guides below are organized the way the decision actually goes: what the relationship says, what has to be true before you can use it, and a worked example with real numbers so you can see the method, not just the result. Each guide lists the open textbook pages it was checked against.
Stoichiometry
Moles, masses, yields and the ratios that connect them. The arithmetic every chemistry course runs on.
| Formula | Says |
|---|---|
Empirical formula%X = (mass X / mass compound) × 100% | An empirical formula gives the simplest whole-number ratio of atoms in a compound. |
Percent yield formulapercent yield = (actual yield / theoretical yield) × 100% | Percent yield compares what a reaction actually produced with the most it could have produced. |
Limiting reactantcompare n(X) / coefficient(X) across reactants; the smallest value is limiting | The limiting reactant is the one that runs out first and therefore caps how much product forms. |
Molar massM = Σ (atoms of each element × atomic mass) | Molar mass is the mass of one mole of a substance in grams per mole, and it equals the sum of the atomic masses in the formula. |
Molecular formulan = molar mass / empirical formula mass | A molecular formula gives the actual number of each kind of atom in one molecule, where the empirical formula gives only the simplest ratio. |
Atomic structure and bonding
Where the electrons are and how atoms hold together.
| Formula | Says |
|---|---|
Electron configuration1s 2s 2p 3s 3p 4s 3d 4p 5s 4d 5p 6s 4f 5d 6p 7s 5f 6d 7p | An electron configuration lists which orbitals an atom's electrons occupy, written as subshell labels with electron counts. |
Lewis structure1 count valence electrons, 2 connect atoms with single bonds, 3 complete octets on outer atoms, 4 put leftovers on the central atom, 5 form multiple bonds if the central atom is short | A Lewis structure is a drawing that shows where every valence electron sits in a molecule or ion, as bonding pairs between atoms and lone pairs on them. |
Covalent bondΔEN = |EN(A) - EN(B)| | A covalent bond is a shared pair of electrons holding two atoms together. |
Solutions, acids and bases
Concentration, dilution, pH and buffers.
| Formula | Says |
|---|---|
pH formulapH = -log[H₃O⁺] | pH is the negative base-10 logarithm of the hydronium ion concentration, so it compresses a huge concentration range onto a readable scale. |
Titrationn(titrant) = M(titrant) × V(titrant) | A titration finds an unknown concentration by adding a solution of known concentration until the reaction is exactly complete. |
Henderson-Hasselbalch equationpH = pKa + log([A⁻] / [HA]) | The Henderson-Hasselbalch equation gives the pH of a buffer from the pKa of its weak acid and the ratio of conjugate base to acid. |
Dilution formulaC₁V₁ = C₂V₂, often written M₁V₁ = M₂V₂ | The dilution formula says concentration times volume stays constant when you add solvent, because the amount of solute never changes. |
Molarity formulaM = mol solute / L solution | Molarity is moles of solute per liter of solution, the concentration unit most chemistry calculations run on. |
Thermodynamics and kinetics
Whether a reaction goes, and how fast.
| Formula | Says |
|---|---|
Nernst equationE_cell = E°_cell - (RT / nF)·ln Q | The Nernst equation gives the cell potential when concentrations are not all standard. |
Hess's lawΔH_reaction = ΣΔH_steps | Hess's law says the enthalpy change of a reaction depends only on where it starts and ends, not on the route taken. |
Half-life formulat½ = ln 2 / k ≈ 0.693 / k | Half-life is the time for half the material present to react or decay. |
Rate lawrate = k[A]^m[B]^n | A rate law states how a reaction's rate depends on the concentrations of its reactants, as a rate constant multiplied by concentrations raised to powers. |
Arrhenius equationk = A·e^(-Ea / RT) | The Arrhenius equation describes how a rate constant grows with temperature. |
Gibbs free energy equationG = H - TS | The Gibbs free energy change combines enthalpy and entropy into one test for spontaneity at constant temperature and pressure. |
Gases and equilibrium
The gas laws and the balance point of a reversible reaction.
| Formula | Says |
|---|---|
Ideal gas lawPV = nRT | The ideal gas law ties pressure, volume, amount and temperature into one relation, PV = nRT. |
How to use a formula sheet well
Start from the quantities you know and the one you want, then find the formula that contains exactly those and nothing you would have to guess. Check its conditions before the algebra, not after: an ideal gas, a dilute solution, a reaction at equilibrium. Write the units through every line, because a unit that does not cancel is the fastest way to catch a wrong formula. And keep one worked example per formula that you can reproduce from memory; that is what turns the sheet into a method.